Journal article
The synthesis of (-)-cis- and (-)-trans-crobarbatic acid
- Abstract:
- The synthesis of both cis- and trans-crobarbatic acid is reported. The five-step sequence proceeds in high yield and with control of both relative and absolute stereochemistry. The key step in the synthesis is the Birch reductive alkylation of a chiral furoic acid which sets the absolute stereochemistry of the products. The stereochemistry of the compounds described was proven unambiguously by X-ray crystallography on one synthetic intermediate and on trans-crobarbatic acid.
- Publication status:
- Published
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- Publisher copy:
- 10.1016/S0957-4166(99)00097-X
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Authors
Bibliographic Details
- Journal:
- TETRAHEDRON-ASYMMETRY
- Volume:
- 10
- Issue:
- 7
- Pages:
- 1315-1322
- Publication date:
- 1999-04-09
- DOI:
- ISSN:
-
0957-4166
- Source identifiers:
-
36983
Item Description
- Language:
- English
- Pubs id:
-
pubs:36983
- UUID:
-
uuid:378ba6ba-84ba-4314-983e-d6f8ec3d3dca
- Local pid:
- pubs:36983
- Deposit date:
- 2012-12-19
Terms of use
- Copyright date:
- 1999
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