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The [2,3] sigmatropic rearrangement of N-benzyl-O-allylhydroxylamines

Abstract:
The rearrangement of a range of N-benzyl-O-allylhydroxylamines to the corresponding N-allylhydroxylamines upon treatment with n-BuLi in THF, followed by reduction to the corresponding N-allylamines, is described. Mechanistic studies of the transformation are consistent with an intramolecular [2,3] sigmatropic rearrangement.
Publication status:
Published

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Publisher copy:
10.1039/b205323n

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
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Journal:
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
Issue:
15
Pages:
1757-1765
Publication date:
2002-01-01
DOI:
EISSN:
1364-5463
ISSN:
1472-7781
Source identifiers:
38385
Language:
English
Pubs id:
pubs:38385
UUID:
uuid:37733825-6995-4cb0-9f24-53acfd387a11
Local pid:
pubs:38385
Deposit date:
2012-12-19

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