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OCTATETRAYNE-LINKED PORPHYRINS - STRETCHED CYCLIC DIMERS AND TRIMERS WITH VERY SPACIOUS CAVITIES

Abstract:: Syntheses are described for two octatetrayne-linked cyclic porphyrin oligomers with extremely spacious cavities. These hosts bind strongly to complementary multidentate guests. Thus, the octatetrayne-linked dimer binds bifunctional ligand bis(4-pyridyl)ethyne with an affinity of 7 × 10 6 dm3 mol-1, and the trimer binds the new 'stretched' trifunctional ligand 1,3,5-tris[(4-pyridyl)ethynyl]benzene with an affinity of 2 × 108 dm3 mol-1 in C 2H2Cl4 at 30°C.

Publication status:: Published

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APA Style

Anderson, H., Walter, C., Vidalferran, A., Hay, R., Lowden, P., & Sanders, J. (1995). OCTATETRAYNE-LINKED PORPHYRINS - STRETCHED CYCLIC DIMERS AND TRIMERS WITH VERY SPACIOUS CAVITIES. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 18, 2275–2279.

MLA Style

Anderson, H., et al. “OCTATETRAYNE-LINKED PORPHYRINS - STRETCHED CYCLIC DIMERS AND TRIMERS WITH VERY SPACIOUS CAVITIES.” JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, no. 18, 1995, pp. 2275–79.

Chicago Style

Anderson, H, C Walter, A Vidalferran, R Hay, P Lowden, and J Sanders. 1995. “OCTATETRAYNE-LINKED PORPHYRINS - STRETCHED CYCLIC DIMERS AND TRIMERS WITH VERY SPACIOUS CAVITIES.” JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, no. 18: 2275–79.
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Publisher copy:: 10.1039/p19950002275

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+ Anderson, H More by this author

Institution:

University of Oxford

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MPLS

Department:

Chemistry

Sub department:

Organic Chemistry

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Author

+ Walter, C More by this author

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Author

+ Vidalferran, A More by this author

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+ Hay, R More by this author

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+ Lowden, P More by this author

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Bibliographic Details

Journal:: JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
Issue:: 18
Pages:: 2275-2279
Publication date:: 1995-09-21
DOI:: 10.1039/p19950002275
EISSN:: 1364-5463
ISSN:: 0300-922X

Item Description

Pubs id:: pubs:51880
UUID:: uuid:373e925a-1aca-4290-9910-9c77ad86b923
Local pid:: pubs:51880
Source identifiers:: 51880
Deposit date:: 2012-12-19

Terms of use

Copyright date:: 1995

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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