Journal article
Voltammetry under high mass transport conditions. The application of the high speed channel electrode to the reduction of pentafluoronitrobenzene
- Abstract:
-
The electroreduction of pentafluoronitrobenzene in dimethylformamide solution resulting in the formation of the dimer, octafluoro-4,4′-dinitro-biphenyl, is studied. The dimeric species is reduced further at the potentials applied to the corresponding di-anion. Microband electrodes are used in conjunction with a high speed channel flow cell to explore the mechanism of this process and to quantify the associated very fast homogeneous kinetics. In particular, the formation of the dimer is seen t...
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- Publication status:
- Published
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- Publisher copy:
- 10.1016/0022-0728(96)04585-8
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Authors
Bibliographic Details
- Journal:
- JOURNAL OF ELECTROANALYTICAL CHEMISTRY
- Volume:
- 411
- Issue:
- 1-2
- Pages:
- 121-127
- Publication date:
- 1996-08-01
- DOI:
- ISSN:
-
0022-0728
- URN:
-
uuid:37319d89-e442-4ebb-bf3f-8987b280cb90
- Source identifiers:
-
118892
- Local pid:
- pubs:118892
Item Description
- Language:
- English
- Keywords:
Terms of use
- Copyright date:
- 1996
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