Journal article icon

Journal article

Voltammetry under high mass transport conditions. The application of the high speed channel electrode to the reduction of pentafluoronitrobenzene

Abstract:

The electroreduction of pentafluoronitrobenzene in dimethylformamide solution resulting in the formation of the dimer, octafluoro-4,4′-dinitro-biphenyl, is studied. The dimeric species is reduced further at the potentials applied to the corresponding di-anion. Microband electrodes are used in conjunction with a high speed channel flow cell to explore the mechanism of this process and to quantify the associated very fast homogeneous kinetics. In particular, the formation of the dimer is seen t...

Expand abstract
Publication status:
Published

Actions


Access Document


Authors


Dryfe, RAW More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
Expand authors...
Journal:
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume:
411
Issue:
1-2
Pages:
121-127
Publication date:
1996-08-01
DOI:
ISSN:
0022-0728
URN:
uuid:37319d89-e442-4ebb-bf3f-8987b280cb90
Source identifiers:
118892
Local pid:
pubs:118892

Terms of use


Metrics



If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP