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Journal article

Reversible recruitment and emission of DO3A-derived lanthanide complexes at ligating molecular films on gold.

Abstract:

The recruitment of DO3A-derived lanthanide complexes by ligation to isophthalic acid and catechol-modified gold surfaces, and their resulting sensitization, is reported herein. Predictably pH-dependent surface recruitment is associated with the expected fingerprint europium and terbium emission characteristics. The intensity of the lanthanide luminescence scales exponentially with spacer length, indicating a strong quenching interaction between the lanthanide and the gold surface. The switcha...

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Publication status:
Published

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Publisher copy:
10.1021/la3046725

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
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Journal:
Langmuir : the ACS journal of surfaces and colloids
Volume:
29
Issue:
5
Pages:
1475-1482
Publication date:
2013-02-01
DOI:
EISSN:
1520-5827
ISSN:
0743-7463
Source identifiers:
375680
Language:
English
Pubs id:
pubs:375680
UUID:
uuid:36af684f-1b5b-4acd-a5fb-f988737816af
Local pid:
pubs:375680
Deposit date:
2013-11-16

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