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Borane to boryl hydride to borylene dihydride: explicit demonstration of boron-to-metal α-hydride migration in aminoborane activation.

Abstract:

The sequence of fundamental steps implicit in the conversion of a dihydroborane to a metal borylene complex have been elucidated for an [Ir(PMe(3))(3)] system. B-H oxidative addition has been applied for the first time to an aminodihydroborane, H(2)BNR(2), leading to the generation of a rare example of a primary boryl complex, L(n)(H)M{B(H)NR(2)}; subsequent conversion to a borylene dihydride proceeds via a novel B-to-M α-hydride migration. The latter step is unprecedented for group 13 ligand...

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Publication status:
Published

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Publisher copy:
10.1021/ja2050748

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Journal:
Journal of the American Chemical Society
Volume:
133
Issue:
30
Pages:
11500-11503
Publication date:
2011-08-05
DOI:
EISSN:
1520-5126
ISSN:
0002-7863
URN:
uuid:367248de-4777-43d8-bd85-d9d162afe5a0
Source identifiers:
166482
Local pid:
pubs:166482
Language:
English

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