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Radiofrequency polarization effects in low-field electron paramagnetic resonance.

Abstract:

Low-field optically detected EPR spectra of photochemically formed transient radical ion pairs are reported for weak circularly and linearly polarized radiofrequency (RF) fields. The spectra are found to be strongly dependent on the polarization and frequency of the RF field and on the angle between the static magnetic field and the plane containing the RF field. The spectra are discussed in terms of resonances arising from Zeeman and hyperfine interactions; the conditions for validity of the...

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Publication status:
Published

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Publisher copy:
10.1039/b907915g

Authors


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Institution:
University of Oxford
Department:
Oxford, MPLS, Physics
Role:
Author
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Institution:
University of Oxford
Department:
Oxford, MSD, RDM, BHF Centre of Research Excellence
Role:
Author
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Journal:
Physical chemistry chemical physics : PCCP
Volume:
11
Issue:
31
Pages:
6573-6579
Publication date:
2009-08-05
DOI:
EISSN:
1463-9084
ISSN:
1463-9076
URN:
uuid:366f93d3-1055-4cee-af6d-cd02a18c560a
Source identifiers:
34809
Local pid:
pubs:34809
Language:
English

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