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ALIGNMENT EFFECTS IN THE MULTIPLE PHOTON IONIZATION OF NITRIC-OXIDE

Abstract:
1+1 resonantly enhanced multiple photon ionisation of NO(X 2Πi) via the A 2Σ+ state at wavelengths near 226 nm gives ion signals which depend upon the value of {norm of matrix}ΔJ{norm of matrix}in the A-X transition, with P, R branch excitation being enhanced over Q branch excitation. The results are interpreted in terms of ionisation of aligned NO A 2Σ+ molecules, and imply that the electron departs primarily as a pσ wave. Implications for the measurements of ground state NO populations via two-step ionisation are discussed. © 1985.
Publication status:
Published

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
CHEMICAL PHYSICS LETTERS
Volume:
113
Issue:
6
Pages:
509-514
Publication date:
1985-01-01
DOI:
ISSN:
0009-2614
Source identifiers:
42398
Language:
English
Pubs id:
pubs:42398
UUID:
uuid:36409d7b-a8b6-4356-94e4-c74e8d20e7c4
Local pid:
pubs:42398
Deposit date:
2012-12-19

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