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Journal article

Permethylpentalene chemistry

Abstract:: A rational solution-phase synthesis of a permethylpentalene (Pn*) ligand precursor for use in organometallic chemistry has been devised through the novel peripheral alkylation of the bicyclo[3.3.0]octane ring system. Tetramethylation of tetramethyl 3,7-dihydroxybicyclo[3.3.0]octa-2,6-diene-2,4,6, 8-tetracarboxylate (1) forms sterically encumbered 2 which exhibits fluxionality. Decarboxylation to 3 followed by facile double dehydrogenation using Br2 affords 4. Nucleophilic addition of the fina...
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Publication status:: Published

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APA Style

Ashley, A., Cowley, A., & O'Hare, D. (2007). Permethylpentalene chemistry. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2007(14), 2239–2242.

MLA Style

Ashley, A., et al. “Permethylpentalene Chemistry.” EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, vol. 2007, no. 14, 2007, pp. 2239–42.

Chicago Style

Ashley, A, A Cowley, and D O'Hare. 2007. “Permethylpentalene Chemistry.” EUROPEAN JOURNAL OF ORGANIC CHEMISTRY 2007 (14): 2239–42.
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Publisher copy:: 10.1002/ejoc.200700033

Authors

+ Ashley, A More by this author

Role:

Author

+ Cowley, A More by this author

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Author

+ O'Hare, D More by this author

Institution:

University of Oxford

Division:

MPLS

Department:

Chemistry

Sub department:

Inorganic Chemistry

Role:

Author

Bibliographic Details

Journal:: EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume:: 2007
Issue:: 14
Pages:: 2239-2242
Publication date:: 2007-05-01
DOI:: 10.1002/ejoc.200700033
EISSN:: 1099-0690
ISSN:: 1434-193X

Item Description

Language:: English
Keywords:: pentalenes

organoceriurn

ligand design

aromaticity

fulvenes
Pubs id:: pubs:51277
UUID:: uuid:3630b9c0-2944-40bc-ab29-1692f1a64c11
Local pid:: pubs:51277
Source identifiers:: 51277
Deposit date:: 2012-12-19

Terms of use

Copyright date:: 2007

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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