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PGSE diffusion studies on chelating phosphine complexes of ruthenium(II). Solvent dependence and ion pairing

Abstract:: PGSE 1H and 19F diffusion data, D values, and 1H,19F HOESY NMR spectra for a series of [RuCl(p-cymene)(BINAP)]X salts, 2a-f, have been recorded in CD2Cl2 (X = BF4- (2a), CF3 SO3- (2b), BArF- (2c), PF6- (2d), SbF6- (2e), Cl- (2f)). The solvent dependence of the D values for 2a-c in methanol, chloroform, dichloromethane, and acetone and the resulting ion-pairing effects are discussed. On the basis of HOESY data, it is suggested that small anions in chloroform solution approach the ruthenium ato...
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APA Style

Kumar, P., Pregosin, P., Goicoechea, J., & Whittlesey, M. (2003). PGSE diffusion studies on chelating phosphine complexes of ruthenium(II). Solvent dependence and ion pairing. ORGANOMETALLICS, 22(14), 2956–2960.

MLA Style

Kumar, P., et al. “PGSE Diffusion Studies on Chelating Phosphine Complexes of Ruthenium(II). Solvent Dependence and Ion Pairing.” ORGANOMETALLICS, vol. 22, no. 14, 2003, pp. 2956–60.

Chicago Style

Kumar, P, P Pregosin, J Goicoechea, and M Whittlesey. 2003. “PGSE Diffusion Studies on Chelating Phosphine Complexes of Ruthenium(II). Solvent Dependence and Ion Pairing.” ORGANOMETALLICS 22 (14): 2956–60.
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Publisher copy:: 10.1021/om030145p

Authors

+ Kumar, P More by this author

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+ Pregosin, P More by this author

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+ Goicoechea, J More by this author

Institution:

University of Oxford

Division:

MPLS

Department:

Chemistry

Sub department:

Inorganic Chemistry

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Author

+ Whittlesey, M More by this author

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Author

Bibliographic Details

Journal:: ORGANOMETALLICS
Volume:: 22
Issue:: 14
Pages:: 2956-2960
Publication date:: 2003-07-07
DOI:: 10.1021/om030145p
EISSN:: 1520-6041
ISSN:: 0276-7333

Item Description

Language:: English
Pubs id:: pubs:38723
UUID:: uuid:35f301ac-fd48-465d-9ffb-d56dcb0f3cbb
Local pid:: pubs:38723
Source identifiers:: 38723
Deposit date:: 2012-12-19

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Copyright date:: 2003

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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