Journal article icon

Journal article

Using the pulsed nature of staircase cyclic voltammetry to determine interfacial electron-transfer rates of adsorbed species.

Abstract:

Staircase cyclic voltammetry (SCV) is the digital counterpart of analog cyclic voltammetry (CV). However, when the redox-active species is adsorbed at the electrode surface, the voltammetric peak shapes (width, height, area, and to a lesser extent the reduction potentials) obtained with SCV can be very different from those of CV, even when small potential steps are used. Like analog CV, SCV provides a straightforward method to estimate and subtract the background and charging currents from th...

Expand abstract
Publication status:
Published

Actions


Access Document


Publisher copy:
10.1021/ac980844p

Authors


Heering, HA More by this author
Mondal, MS More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Journal:
Analytical chemistry
Volume:
71
Issue:
1
Pages:
174-182
Publication date:
1999-01-05
DOI:
EISSN:
1520-6882
ISSN:
0003-2700
URN:
uuid:35d03b75-d5ff-4e9a-b881-948dadb7b627
Source identifiers:
36886
Local pid:
pubs:36886
Language:
English

Terms of use


Metrics



If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP