Journal article

A remarkable switch from a diamination to a hydrohydrazination catalyst and observation of an unprecedented catalyst resting state.

Abstract:: A small change with a big effect: Reaction of the titanium complex 1 with terminal alkynes gave the unusual acetylide-vinylhydrazide(1-) compounds 2 (R=4-C6H4X (X=Me, CF3, OMe), C 6F5, SiMe3) as hydrohydrazination intermediates. In contrast, a complex similar to 1 with bulkier trimethylsilyl substituents in place of the isopropyl groups is known to catalyze the 1,2-diamination of alkynes with hydrazines. Copyright © 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim.

Publication status:: Published

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APA Style

Schwarz, A., Onn, C., & Mountford, P. (2012). A remarkable switch from a diamination to a hydrohydrazination catalyst and observation of an unprecedented catalyst resting state. Angewandte Chemie (International Ed. in English), 51(49), 12298–12302.

MLA Style

Schwarz, A., et al. “A Remarkable Switch from a Diamination to a Hydrohydrazination Catalyst and Observation of an Unprecedented Catalyst Resting State.” Angewandte Chemie (International Ed. in English), vol. 51, no. 49, 2012, pp. 12298–302.

Chicago Style

Schwarz, A, C Onn, and P Mountford. 2012. “A Remarkable Switch from a Diamination to a Hydrohydrazination Catalyst and Observation of an Unprecedented Catalyst Resting State.” Angewandte Chemie (International Ed. in English) 51 (49): 12298–302.
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Publisher copy:: 10.1002/anie.201206249

Authors

+ Schwarz, A More by this author

Role:: Author

+ Onn, C More by this author

Role:: Author

+ Mountford, P More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author

Journal:: Angewandte Chemie (International ed. in English) More from this journal
Volume:: 51
Issue:: 49
Pages:: 12298-12302
Publication date:: 2012-12-01
DOI:: 10.1002/anie.201206249
EISSN:: 1521-3773
ISSN:: 1433-7851

Language:: English
Keywords:: hydrohydrazination

hydrazide complexes

titanium

homogeneous catalysis

hydrazones
Pubs id:: pubs:358298
UUID:: uuid:35bf94ba-838b-42b8-bc10-4fa28314a844
Local pid:: pubs:358298
Source identifiers:: 358298
Deposit date:: 2013-11-17

Terms of use

Copyright date:: 2012

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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