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Ternary self-assemblies in water: forming a pentanuclear ReLn4 assembly by association of binuclear lanthanide binding pockets with fac-Re(CO)3(dinicotinate)2Cl.

Abstract:
The self-assembly of higher order structures in water is realised by using the association of 1,3-biscarboxylates to binuclear meta-xylyl bridged DO3A complexes. Two dinicotinate binding sites are placed at a right-angle in a rhenium complex, which is shown to form a 1 : 2 complex with α,α'-bis(Eu·DO3A)-5-amino-m-xylene.
Publication status:
Published

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Publisher copy:
10.1039/c3dt51705e

Authors


Blackburn, OA More by this author
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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Sørensen, TJ More by this author
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Journal:
Dalton transactions (Cambridge, England : 2003)
Volume:
42
Issue:
46
Pages:
16255-16258
Publication date:
2013-12-05
DOI:
EISSN:
1477-9234
ISSN:
1477-9226
URN:
uuid:3526eb50-6f7a-4e2c-899c-1b5b23999b3c
Source identifiers:
418362
Local pid:
pubs:418362
Language:
English

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