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Voltammetric characteristics of graphite electrodes modified with microdroplets of n-butylferrocene

Abstract:

We report the voltammetry of basal plane pyrolytic graphite electrodes partially covered with immobilised microdroplets of n-butylferrocene and immersed in various aqueous electrolyte solutions. Oxidation of the redox-active oil droplets to form the n-butylferrocinium cation takes place with the expulsion of the cation from the oil phase. The dissolution process is accompanied by the formation of ion pairs between the n-butylferrocinium cation and the counter anion in the aqueous solution; ad...

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Publication status:
Published

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Authors


Wadhawan, JD More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Journal:
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume:
533
Issue:
1-2
Pages:
71-84
Publication date:
2002-09-20
DOI:
ISSN:
0022-0728
URN:
uuid:345ea7d6-0c22-4250-813b-c106b870e393
Source identifiers:
38408
Local pid:
pubs:38408

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