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Contrasting reactivity of anionic boron- and gallium-containing NHC analogues: E-C vs. E-M bond formation (E = B, Ga).

Abstract:
The anionic Group 13 NHC analogues [(CHNDipp)(2)E](-) (E = B or Ga) display contrasting reactivity towards the half-sandwich titanium imido complex Cp*TiCl(NtBu)py; while the gallium system undergoes salt metathesis yielding the first example of a titanium gallyl compound, the more nucleophilic boryl anion generates a dearomatized pyridyl fragment via attack at the ligand 2-position.
Publication status:
Published

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Publisher copy:
10.1039/c0cc02572k

Authors


Protchenko, AV More by this author
Vidovic, D More by this author
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Journal:
Chemical communications (Cambridge, England)
Volume:
46
Issue:
45
Pages:
8546-8548
Publication date:
2010-12-05
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
URN:
uuid:31b4f4f2-a777-45ed-945e-12cff3733697
Source identifiers:
71167
Local pid:
pubs:71167
Language:
English

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