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Chiral selection in the formation of borates from racemic binaphthols and related diols

Abstract:
A series of racemic or stereochemically labile chiral borate anions based on the 2,2′-biphenol motif was investigated. All borates were homochiral in the solid state, although in some cases the heterochiral diastereomers were computed to be thermodynamically preferred (DFT). The crystallographic preference for the homochiral diastereomer was attributed to its lower bulk, higher molecular symmetry, and the therewith associated better packing ability.
Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1039/c0ce00709a

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Institution:
University of Oxford
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Institution:
University of Oxford
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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
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Funding agency for:
Brown, JM
Publisher:
Royal Society of Chemistry Publisher's website
Journal:
CRYSTENGCOMM Journal website
Volume:
13
Issue:
8
Pages:
2923-2929
Publication date:
2011-04-05
DOI:
EISSN:
1466-8033
ISSN:
1466-8033
URN:
uuid:31999dd9-c516-4735-af60-d5641d21ffce
Source identifiers:
135058
Local pid:
pubs:135058

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