Chiral selection in the formation of borates from racemic binaphthols and related diols
- A series of racemic or stereochemically labile chiral borate anions based on the 2,2′-biphenol motif was investigated. All borates were homochiral in the solid state, although in some cases the heterochiral diastereomers were computed to be thermodynamically preferred (DFT). The crystallographic preference for the homochiral diastereomer was attributed to its lower bulk, higher molecular symmetry, and the therewith associated better packing ability.
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- Peer reviewed
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- Royal Society of Chemistry
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- This journal is © The Royal Society of Chemistry 2011. The full text of this article is not available in ORA. You may be able to access the article via the publisher copy link above.
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