Journal article
Photoelectrochemistry of bromonitrobenzenes: mechanism and photoelectrochemically-induced halex reactions
- Abstract:
-
The theory for homogeneous ECrevE, ECrevCE and ECECE mechanisms at macroscopically large channel electrodes is derived. The photoelectrochemical reductions of para-bromonitrobenzene and 2,4-dibromonitrobenzene in acetonitrile solutions and at macroscopic platinum channel electrodes are studied using irradiation at 330 and 470 nm, corresponding to absorption bands in the corresponding radical anions. The former compound is shown to follow a homogeneous ECrevCE pathway in acetonitrile solutions...
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- Publication status:
- Published
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- Publisher copy:
- 10.1016/S0022-0728(02)01064-1
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Bibliographic Details
- Journal:
- JOURNAL OF ELECTROANALYTICAL CHEMISTRY
- Volume:
- 533
- Issue:
- 1-2
- Pages:
- 33-70
- Publication date:
- 2002-09-20
- DOI:
- ISSN:
-
0022-0728
- Source identifiers:
-
38407
Item Description
- Language:
- English
- Keywords:
- UUID:
-
uuid:30f48caf-e43b-4a86-9596-33c4c7bf2126
- Local pid:
- pubs:38407
- Deposit date:
- 2012-12-19
Terms of use
- Copyright date:
- 2002
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