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Photoelectrochemistry of bromonitrobenzenes: mechanism and photoelectrochemically-induced halex reactions

Abstract:

The theory for homogeneous ECrevE, ECrevCE and ECECE mechanisms at macroscopically large channel electrodes is derived. The photoelectrochemical reductions of para-bromonitrobenzene and 2,4-dibromonitrobenzene in acetonitrile solutions and at macroscopic platinum channel electrodes are studied using irradiation at 330 and 470 nm, corresponding to absorption bands in the corresponding radical anions. The former compound is shown to follow a homogeneous ECrevCE pathway in acetonitrile solutions...

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Publication status:
Published

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Journal:
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume:
533
Issue:
1-2
Pages:
33-70
Publication date:
2002-09-20
DOI:
ISSN:
0022-0728
URN:
uuid:30f48caf-e43b-4a86-9596-33c4c7bf2126
Source identifiers:
38407
Local pid:
pubs:38407

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