- Abstract:
-
The theory for homogeneous ECrevE, ECrevCE and ECECE mechanisms at macroscopically large channel electrodes is derived. The photoelectrochemical reductions of para-bromonitrobenzene and 2,4-dibromonitrobenzene in acetonitrile solutions and at macroscopic platinum channel electrodes are studied using irradiation at 330 and 470 nm, corresponding to absorption bands in the corresponding radical anions. The former compound is shown to follow a homogeneous ECrevCE pathway in acetonitrile solutions...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1016/S0022-0728(02)01064-1
-
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- Journal:
- JOURNAL OF ELECTROANALYTICAL CHEMISTRY
- Volume:
- 533
- Issue:
- 1-2
- Pages:
- 33-70
- Publication date:
- 2002-09-20
- DOI:
- ISSN:
-
0022-0728
- URN:
-
uuid:30f48caf-e43b-4a86-9596-33c4c7bf2126
- Source identifiers:
-
38407
- Local pid:
- pubs:38407
- Copyright date:
- 2002
Journal article
Photoelectrochemistry of bromonitrobenzenes: mechanism and photoelectrochemically-induced halex reactions
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