Journal article icon

Journal article

A homologous series of first-row transition-metal complexes of 2,2'-bipyridine and their ligand radical derivatives: trends in structure, magnetism, and bonding.

Abstract:

The organometallic first-row transition-metal complexes [M(2,2'-bipy)(mes)2] (M = Cr (1), Mn (2), Co (4), Ni (5); 2,2'-bipy = 2,2'-bipyridine; mes = 2,4,6-Me3C6H2) were reacted with potassium and a suitable alkali-metal sequestering agent to yield salts of the anionic species [M(2,2'-bipy)(mes)2](-). The neutral parent compounds and their corresponding anionic congeners were characterized by single-crystal X-ray diffraction in [Cr(2,2'-bipy)(mes)2]·1.5C6H6, [Mn(2,2'-bipy)(mes)2], [Co(2,2'-bip...

Expand abstract
Publication status:
Published

Actions


Access Document


Publisher copy:
10.1021/ic301587f

Authors


Krämer, T More by this author
Herchel, R More by this author
McGrady, JE More by this author
Expand authors...
Journal:
Inorganic chemistry
Volume:
51
Issue:
22
Pages:
12301-12312
Publication date:
2012-11-05
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
URN:
uuid:30da17e0-c34e-45cc-a182-acfe4a7183f6
Source identifiers:
358294
Local pid:
pubs:358294
Language:
English

Terms of use


Metrics



If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP