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Solid and solution state structures of a reversible molecular oxygen-carrying molybdenum porphyrin dioxygen complex

Abstract:
The molecular structure of a reversible oxygen carrier, MoVIO(tmp)(O2) has been characterized by X-ray crystallography. Oxo and dioxygen ligands are actually coordinated with cis conformation, which leads to a saddle-like distortion of the porphyrin ring. The result of 2D ROESY shows the distortion of the porphyrin ring is retained in solution.
Publication status:
Published

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Publisher copy:
10.1246/cl.2000.102

Authors


Fujihara, T More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Umakoshi, K More by this author
Tachibana, J More by this author
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Journal:
CHEMISTRY LETTERS
Issue:
2
Pages:
102-103
Publication date:
2000-02-05
DOI:
EISSN:
1348-0715
ISSN:
0366-7022
URN:
uuid:2f5db2e5-d61c-4136-9a8f-1692a24bb663
Source identifiers:
115937
Local pid:
pubs:115937
Language:
English

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