- Abstract:
-
In mercury superconducting cuprates synthesized at high pressure, partial carbon substitution on the mercury site occurs when the precursors are not absolutely carbon free. Hg-12(n-1)n samples made from carbonate-containing precursors show lower Tcs and smaller c parameter. A model of the structural arrangement of the CO3 -2 groups is proposed from neutron diffraction data and crystal-chemistry considerations. The third oxygen of the oxyanion is situated in the (Hg,C)O∂ layer and hinders the ...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1016/S0921-4534(97)00211-6
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- Volume:
- 282
- Issue:
- PART 1
- Pages:
- 65-68
- Publication date:
- 1997-08-05
- DOI:
- ISSN:
-
0921-4534
- URN:
-
uuid:2dc73164-2c93-4617-8944-01e5a47f578c
- Source identifiers:
-
66388
- Local pid:
- pubs:66388
- Copyright date:
- 1997
Conference
High pressure synthesis and structure of the superconducting mercury cuprates (Hg1-xMx)Ba2Can-1CunO2+2n+delta with M = C, S.
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