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Electrochemical probing of photochemical reactions inside femtolitre droplets confined to electrodes.

Abstract:

Random ensembles of femtolitre-volume droplets containing redox active, photosensitive compounds immobilised on an electrode substrate permit photoelectrochemical studies within femtometric environments. Two chemical systems are described; the first is the N,N,N',N'-tetrahexyl-para-phenylenediamine redox-catalysed photochemical debromination of the anaesthetic reagent halothane; the second is the photoinduced electron transfer from excited chlorophyll a to vitamin K1, which has possible poten...

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Publication status:
Published

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Publisher copy:
10.1002/cphc.200300845

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
Journal:
Chemphyschem : a European journal of chemical physics and physical chemistry
Volume:
4
Issue:
11
Pages:
1211-1215
Publication date:
2003-11-05
DOI:
EISSN:
1439-7641
ISSN:
1439-4235
URN:
uuid:2d6f7898-f3d8-45c4-b32d-7619efe2d820
Source identifiers:
32568
Local pid:
pubs:32568

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