Journal article
Simple efficient synthesis of strongly luminescent polypyrene with intrinsic conductivity and high carbon yield by chemical oxidative polymerization of pyrene.
- Abstract:
-
A wholly aromatic polypyrene was synthesized by direct chemical oxidative polymerization of pyrene with ferric chloride as oxidant in hexane/nitromethane. Successful synthesis of polypyrene was thoroughly confirmed by IR, UV/Vis, 1D (1)H NMR, 2D (1)H-(1)H COSY, 2D (1)H-(13)C HSQC, MALDI-TOF MS, elemental analysis, and X-ray diffraction methods. The results indicated that the polypyrene was formed mainly through dehydro coupling between 2- or 1- and 2'- or 1'-positions on pyrene rings having a...
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- Publication status:
- Published
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- Publisher copy:
- 10.1002/chem.200902621
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Bibliographic Details
- Journal:
- Chemistry (Weinheim an der Bergstrasse, Germany)
- Volume:
- 16
- Issue:
- 16
- Pages:
- 4803-4813
- Publication date:
- 2010-04-01
- DOI:
- EISSN:
-
1521-3765
- ISSN:
-
0947-6539
- Source identifiers:
-
58682
Item Description
- Language:
- English
- Keywords:
- Pubs id:
-
pubs:58682
- UUID:
-
uuid:2cc87e29-6365-4ab4-a76b-79d8b6b41966
- Local pid:
- pubs:58682
- Deposit date:
- 2012-12-19
Terms of use
- Copyright date:
- 2010
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