Simple efficient synthesis of strongly luminescent polypyrene with intrinsic conductivity and high carbon yield by chemical oxidative polymerization of pyrene.

Li, XG; Liu, YW; Huang, MR; Peng, S; Gong, LZ; Moloney, MG

Abstract:

A wholly aromatic polypyrene was synthesized by direct chemical oxidative polymerization of pyrene with ferric chloride as oxidant in hexane/nitromethane. Successful synthesis of polypyrene was thoroughly confirmed by IR, UV/Vis, 1D (1)H NMR, 2D (1)H-(1)H COSY, 2D (1)H-(13)C HSQC, MALDI-TOF MS, elemental analysis, and X-ray diffraction methods. The results indicated that the polypyrene was formed mainly through dehydro coupling between 2- or 1- and 2'- or 1'-positions on pyrene rings having a...

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APA Style

Li, X. G., Liu, Y. W., Huang, M. R., Peng, S., Gong, L. Z., & Moloney, M. G. (2010). Simple efficient synthesis of strongly luminescent polypyrene with intrinsic conductivity and high carbon yield by chemical oxidative polymerization of pyrene. Chemistry (Weinheim an Der Bergstrasse, Germany), 16(16), 4803–4813.

MLA Style

Li, X. G., et al. “Simple Efficient Synthesis of Strongly Luminescent Polypyrene with Intrinsic Conductivity and High Carbon Yield by Chemical Oxidative Polymerization of Pyrene.” Chemistry (Weinheim an Der Bergstrasse, Germany), vol. 16, no. 16, 2010, pp. 4803–13.

Chicago Style

Li, XG, YW Liu, MR Huang, S Peng, LZ Gong, and MG Moloney. 2010. “Simple Efficient Synthesis of Strongly Luminescent Polypyrene with Intrinsic Conductivity and High Carbon Yield by Chemical Oxidative Polymerization of Pyrene.” Chemistry (Weinheim an Der Bergstrasse, Germany) 16 (16): 4803–13.
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