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Simple efficient synthesis of strongly luminescent polypyrene with intrinsic conductivity and high carbon yield by chemical oxidative polymerization of pyrene.

Abstract:

A wholly aromatic polypyrene was synthesized by direct chemical oxidative polymerization of pyrene with ferric chloride as oxidant in hexane/nitromethane. Successful synthesis of polypyrene was thoroughly confirmed by IR, UV/Vis, 1D (1)H NMR, 2D (1)H-(1)H COSY, 2D (1)H-(13)C HSQC, MALDI-TOF MS, elemental analysis, and X-ray diffraction methods. The results indicated that the polypyrene was formed mainly through dehydro coupling between 2- or 1- and 2'- or 1'-positions on pyrene rings having a...

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Publication status:
Published

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Publisher copy:
10.1002/chem.200902621

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Journal:
Chemistry (Weinheim an der Bergstrasse, Germany)
Volume:
16
Issue:
16
Pages:
4803-4813
Publication date:
2010-04-05
DOI:
EISSN:
1521-3765
ISSN:
0947-6539
URN:
uuid:2cc87e29-6365-4ab4-a76b-79d8b6b41966
Source identifiers:
58682
Local pid:
pubs:58682

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