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Diode laser based studies of the UV photolysis of molecular iodine.

Abstract:

The photolysis of molecular iodine at 193 and 248 nm has been studied by diode laser based frequency-modulated (FM) absorption spectroscopy with detection of the nascent iodine photofragment via the I((2)P(1/2)-(2)P(3/2)) transition at 1.315 microm. Use of narrow band radiation enables nascent measurements with sufficient speed resolution to allow both the character of the initial electronic transition and speed of the fragments to be determined. The time dependence of the integrated area of ...

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Publication status:
Published

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Publisher copy:
10.1039/b906401j

Authors


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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Richmond, G More by this author
Ritchie, GA More by this author
Journal:
Physical chemistry chemical physics : PCCP
Volume:
11
Issue:
30
Pages:
6415-6423
Publication date:
2009-08-05
DOI:
EISSN:
1463-9084
ISSN:
1463-9076
URN:
uuid:2ca56122-3089-4dce-9881-9942d4d3f64f
Source identifiers:
34921
Local pid:
pubs:34921

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