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Modification and implications of changes in electrochemical responses encountered when undertaking deoxygenation in ionic liquids.

Abstract:

Physicochemical changes and substantially modified electrochemical behavior have been reported when ionic liquids are degassed with nitrogen. In conventional experiments in aqueous and organic media, degassing with N(2) is commonly used to remove the electroactive dissolved oxygen. However, in hydrophilic ionic liquid media, degassing with N(2) removes not only the dissolved oxygen but also a significant amount of the adventitious water present. Given the low viscosity of water, this in turn ...

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Publication status:
Published

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Publisher copy:
10.1021/ac100378g

Authors


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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
O'Mahony, AM More by this author
Rogers, EI More by this author
Journal:
Analytical chemistry
Volume:
82
Issue:
9
Pages:
3856-3861
Publication date:
2010-05-05
DOI:
EISSN:
1520-6882
ISSN:
0003-2700
URN:
uuid:2bf3c318-8163-48fc-ad39-907a527e4185
Source identifiers:
53299
Local pid:
pubs:53299
Language:
English

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