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Fully state-selected VMI study of the near-threshold photodissociation of NO(2): variation of the angular anisotropy parameter.

Abstract:

Velocity-map ion imaging (VMI) has been used to study the angular distribution of the NO fragment generated in the photodissociation of NO(2) at a variety of photolysis wavelengths. Images were recorded for the channels NO (2)Pi(1/2) (v = 0, J= 3/2, 11/2 and 21/2) + O ((3)P(2,1)), for excitation energies ranging from the onset (E(avl)/hc = 0 cm(-1)) to E(avl)/hc approximately 900 cm(-1). The angular anisotropy parameter beta was obtained as a function of available energy. Photofragment multip...

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Publication status:
Published

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Publisher copy:
10.1039/b706428d

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
Journal:
Physical chemistry chemical physics : PCCP
Volume:
9
Issue:
42
Pages:
5656-5663
Publication date:
2007-11-05
DOI:
EISSN:
1463-9084
ISSN:
1463-9076
URN:
uuid:2bb38f64-28db-4b6a-bda2-c77f5585238c
Source identifiers:
34020
Local pid:
pubs:34020
Language:
English

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