Journal article

Electronic delocalization in two and three dimensions: differential aggregation in indium ‘metalloid’ clusters

Abstract:: Reduction of indium boryl precursors to give two- and three-dimensional M-M bonded networks is influenced by the choice of supporting ligand. While the unprecedented nanoscale cluster [In68(boryl)12]- (with an In12@In44@In12(boryl)12 concentric structure), can be isolated from the potassium reduction of a bis(boryl)indium(III) chloride precursor, analogous reduction of the corresponding (benzamidinate)In^III Br(boryl) system gives a nearplanar (and weakly aromatic) tetranuclear [In4(boryl)4]^2- system.

Publication status:: Published

Peer review status:: Peer reviewed

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APA Style

Aldridge, S., Protchenko, A., Urbano, J., Abdalla, J., Campos, J., Vidovic, D., Schwarz, A., Blake, M., Mountford, P., & Jones, C. (2017). Electronic delocalization in two and three dimensions: differential aggregation in indium ‘metalloid’ clusters. Angewandte Chemie International Edition, 56(47), 15098–15102.

MLA Style

Aldridge, S., et al. “Electronic Delocalization in Two and Three Dimensions: Differential Aggregation in Indium ‘Metalloid’ Clusters.” Angewandte Chemie International Edition, vol. 56, no. 47, Wiley, 2017, pp. 15098–102.

Chicago Style

Aldridge, S, A Protchenko, J Urbano, J Abdalla, J Campos, D Vidovic, A Schwarz, M Blake, P Mountford, and C Jones. 2017. “Electronic Delocalization in Two and Three Dimensions: Differential Aggregation in Indium ‘Metalloid’ Clusters.” Angewandte Chemie International Edition 56 (47): 15098–102.
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Files:: Electronic delocalization in two and three dimensions - Differ...

(Preview, Accepted manuscript, pdf, 6.5MB, Terms of use)

Publisher copy:: 10.1002/anie.201708496

Authors

+ Aldridge, S More by this author

Institution:: University of Oxford
Oxford college:: Queens College
Role:: Author

+ Protchenko, A More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author

+ Urbano, J More by this author

Role:: Author

+ Abdalla, J More by this author

Role:: Author

+ Campos, J More by this author

Role:: Author

More authors...

+ Leverhulme Trust More from this funder

Grant:: F/08 699/E

+ Engineering and Physical Sciences Research Council More from this funder

Grant:: EP/L025000/1

Publisher:: Wiley
Journal:: Angewandte Chemie International Edition More from this journal
Volume:: 56
Issue:: 47
Pages:: 15098-15102
Publication date:: 2017-09-22
Acceptance date:: 2017-09-22
DOI:: 10.1002/anie.201708496
EISSN:: 1521-3757
ISSN:: 1433-7851

Keywords:: metal cluster

indium

gallium

Group 13

boryl
Pubs id:: pubs:730302
UUID:: uuid:2b79dc51-d2e8-4d77-a2e5-7977e62e9455
Local pid:: pubs:730302
Source identifiers:: 730302
Deposit date:: 2017-09-22

Terms of use

Copyright holder:: Wiley‐VCH Verlag GmbH and Co
Copyright date:: 2017
Notes:: © 2017 Wiley‐VCH Verlag GmbH and Co. KGaA, Weinheim. This is the accepted manuscript version of the article. The final version is available online from Wiley at: https://doi.org/10.1002/anie.201708496

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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