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Electronic delocalization in two and three dimensions: differential aggregation in indium ‘metalloid’ clusters

Abstract:
Reduction of indium boryl precursors to give two- and three-dimensional M-M bonded networks is influenced by the choice of supporting ligand. While the unprecedented nanoscale cluster [In68(boryl)12]- (with an In12@In44@In12(boryl)12 concentric structure), can be isolated from the potassium reduction of a bis(boryl)indium(III) chloride precursor, analogous reduction of the corresponding (benzamidinate)In^III Br(boryl) system gives a nearplanar (and weakly aromatic) tetranuclear [In4(boryl)4]^2- system.
Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted manuscript

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Publisher copy:
10.1002/anie.201708496

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Department:
Queens College
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Author
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Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
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Publisher:
Wiley Publisher's website
Journal:
Angewandte Chemie International Edition Journal website
Volume:
56
Issue:
47
Pages:
15098-15102
Publication date:
2017-09-22
Acceptance date:
2017-09-22
DOI:
EISSN:
1521-3757
ISSN:
1433-7851
Pubs id:
pubs:730302
URN:
uri:2b79dc51-d2e8-4d77-a2e5-7977e62e9455
UUID:
uuid:2b79dc51-d2e8-4d77-a2e5-7977e62e9455
Local pid:
pubs:730302

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