Journal article icon

Journal article

Phosphoramidate-supported Cp*Ir(III) Aminoborane H2B=NR2 complexes: synthesis, structure, and solution dynamics.

Abstract:
Reaction of the aminoboranes H2B=NR2 (R = iPr or Cy) with the cationic Cp*Ir(III) phosphoramidate complex, [Cp*Ir(κ2-N,O-Xyl(N)P(O)(OEt)2)][BArF4] generates the aminoborane complexes [Cp*Ir(H)(κ1-N-η2-HB-Xyl(N)P(OBHNR2)(OEt)2][BArF4] (R = iPr or Cy) in which coordination of a P=O bond with boron weakens the B=N multiple bond.For these complexes, solution- and solid-state as well as DFT computational techniques have been employed to substantiate B-N bond rotation of the coordinated aminoborane.
Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted manuscript

Actions


Access Document


Files:
Publisher copy:
10.1002/chem.201600951

Authors


Drover, MW More by this author
Schafer, LL More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Publisher:
Wiley Publisher's website
Journal:
Chemistry - A European Journal Journal website
Volume:
22
Issue:
20
Pages:
6793–6797
Publication date:
2016-03-31
DOI:
EISSN:
1521-3765
ISSN:
0947-6539
URN:
uuid:2b46132a-bc11-4a07-9796-0dee0cd7fd2b
Source identifiers:
609508
Local pid:
pubs:609508

Terms of use


Metrics



If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP