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Influence of electrochemical properties in determining the sensitivity of [4Fe-4S] clusters in proteins to oxidative damage.

Abstract:

Interconversion between [4Fe-4S] cubane and [3Fe-4S] cuboidal states represents one of the simplest structural changes an iron-sulphur cluster can undertake. This reaction is implicated in oxidative damage and in modulation of the activity and regulation of certain enzymes, and it is therefore important to understand the factors governing cluster stability and the processes that activate cluster conversion. In the present study, protein film voltammetry has been used to induce and monitor the...

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Publication status:
Published

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Publisher copy:
10.1042/0264-6021:3600717

Authors


Tilley, GJ More by this author
Burgess, BK More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Journal:
The Biochemical journal
Volume:
360
Issue:
Pt 3
Pages:
717-726
Publication date:
2001-12-05
DOI:
EISSN:
1470-8728
ISSN:
0264-6021
URN:
uuid:2a9635e4-f45c-4d3d-a15b-7e674172328f
Source identifiers:
32006
Local pid:
pubs:32006

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