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CHRONOAMPEROMETRY AT CHANNEL ELECTRODES - A GENERAL COMPUTATIONAL APPROACH

Abstract:

A conceptually simple and computationally efficient implicit approach to the simulation of current/time transients at the channel electrode is presented. The generality of the method is illustrated with reference to the simple case of a step between potentials corresponding to zero and transport-limited currents for a simple redox reaction (where good agreement with existing analytical theory is found), to ECE and to DISP1 processes, and finally to the case of double-potential steps. The latt...

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Publication status:
Published

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Publisher copy:
10.1021/j100172a075

Authors


COMPTON, R More by this author
Journal:
JOURNAL OF PHYSICAL CHEMISTRY
Volume:
95
Issue:
19
Pages:
7538-7542
Publication date:
1991-09-19
DOI:
EISSN:
1541-5740
ISSN:
0022-3654
URN:
uuid:2a41cd10-64cf-47c0-9d04-9885be7b1b4f
Source identifiers:
43665
Local pid:
pubs:43665
Language:
English

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