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Reactions at the solid-liquid interface: surface-controlled dissolution of solid particles. The dissolution of potassium bicarbonate in dimethylformamide.

Abstract:

We present a mathematical model for the surface-controlled dissolution of solid particles. This is applied to the dissolution of a solid having different particle size distribution functions: those of a monodispersed solid containing particles of all one size, a two-size-particle distribution, and a Gaussian distribution of the particle sizes. The dissolution of potassium bicarbonate in dimethylformamide is experimentally studied indirectly at elevated temperatures. We monitor the dissolution...

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Publication status:
Published

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Publisher copy:
10.1021/jp040508e

Authors


Forryan, CL More by this author
Klymenko, OV More by this author
Brennan, CM More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Journal:
The journal of physical chemistry. B
Volume:
109
Issue:
7
Pages:
2862-2872
Publication date:
2005-02-05
DOI:
EISSN:
1520-5207
ISSN:
1520-6106
URN:
uuid:29e618f8-a633-481d-bc54-d37f02fb4954
Source identifiers:
33547
Local pid:
pubs:33547

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