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An approach to hyperolactone C and analogues using late stage conjugate addition on an oxonium ylide-derived spirofuranone.

Abstract:
A stereocontrolled synthesis of norphenyl hyperolactone C together with its utility as a direct precursor to the anti-HIV agent hyperolactone C and analogues by addition of organolithiums, are described. Preliminary studies to access this key building block in a catalytic enantioselective manner are also reported.
Publication status:
Published

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Publisher copy:
10.1039/c3ob41251b

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
Role:
Author
Journal:
Organic and biomolecular chemistry
Volume:
11
Issue:
32
Pages:
5362-5369
Publication date:
2013-08-05
DOI:
EISSN:
1477-0539
ISSN:
1477-0520
URN:
uuid:28cba5f4-9877-4b27-8d0f-620ceb9b9a32
Source identifiers:
414670
Local pid:
pubs:414670

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