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Journal article

New and versatile routes to zirconium imido dichloride compounds.

Abstract:

Reactions of zirconium dialkyl- or bis(amido)-dichloride complexes "[Zr(CH2SiMe3)2Cl2(Et2O)2]" or [Zr(NMe2)2Cl2(THF)2] with primary alkyl and aryl amines are described. Reaction of "[Zr(CH2SiMe3)2Cl2(Et2O)2]" with RNH2 in THF afforded dimeric [Zr2(mu-NR)2Cl4(THF)4](R=2,6-C6H3iPr2 (1), 2,6-C6H3Me2 (2) or Ph (3)), [Zr2(mu-NR)2Cl4(THF)3](R=tBu (5), iPr (6), CH2Ph (7)), or the "ate" complex [Zr2(mu-NC6F5)2Cl6(THF)2{Li(THF)3}2](4, the LiCl coming from the in situ prepared "[Zr(CH2SiMe3)2Cl2(Et2O)2...

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Publication status:
Published

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Publisher copy:
10.1039/b500507h

Authors


Dubberley, SR More by this author
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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Journal:
Dalton transactions (Cambridge, England : 2003)
Issue:
8
Pages:
1448-1458
Publication date:
2005-04-05
DOI:
EISSN:
1477-9234
ISSN:
1477-9226
URN:
uuid:28a4d467-5dee-4f70-898a-2c74010ad34d
Source identifiers:
51044
Local pid:
pubs:51044

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