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Cationic silyldiazenido complexes of the Fe(diphosphine)2(N2) platform: structural and electronic models for an elusive first intermediate in N2 fixation

Abstract:
The first cationic Fe silyldiazenido complexes, [Fe(PP)2(NN-SiMe3)]+[BArF4]- (PP = dmpe/depe), have been synthesised and thoroughly characterised. Computational studies show the compounds to be useful structural and electronic surrogates for the more elusive [Fe(PP)2(NN-H)]+, which are postulated intermediates in the H+/e- mediated fixation of N2 by Fe(PP)2(N2) species.
Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted Manuscript

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Publisher copy:
10.1039/c7cc04188h

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Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Inorganic Chemistry
Oxford college:
St Hughs College
Role:
Author
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Publisher:
Royal Society of Chemistry Publisher's website
Journal:
Chemical Communications Journal website
Volume:
53
Issue:
54
Pages:
7657-7660
Publication date:
2017-07-19
Acceptance date:
2017-06-17
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
Pubs id:
pubs:702390
URN:
uri:2899043d-8859-41ac-a454-62bbbc8f3176
UUID:
uuid:2899043d-8859-41ac-a454-62bbbc8f3176
Local pid:
pubs:702390
Language:
English

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