- Abstract:
- The first cationic Fe silyldiazenido complexes, [Fe(PP)2(NN-SiMe3)]+[BArF4]- (PP = dmpe/depe), have been synthesised and thoroughly characterised. Computational studies show the compounds to be useful structural and electronic surrogates for the more elusive [Fe(PP)2(NN-H)]+, which are postulated intermediates in the H+/e- mediated fixation of N2 by Fe(PP)2(N2) species.
- Publication status:
- Published
- Peer review status:
- Peer reviewed
- Version:
- Accepted Manuscript
- Files:
-
-
(pdf, 608.4KB)
-
- Publisher copy:
- 10.1039/c7cc04188h
-
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- Publisher:
- Royal Society of Chemistry Publisher's website
- Journal:
- Chemical Communications Journal website
- Volume:
- 53
- Issue:
- 54
- Pages:
- 7657-7660
- Publication date:
- 2017-07-19
- Acceptance date:
- 2017-06-17
- DOI:
- EISSN:
-
1364-548X
- ISSN:
-
1359-7345
- Pubs id:
-
pubs:702390
- URN:
-
uri:2899043d-8859-41ac-a454-62bbbc8f3176
- UUID:
-
uuid:2899043d-8859-41ac-a454-62bbbc8f3176
- Local pid:
- pubs:702390
- Language:
- English
- Copyright holder:
- Piascik et al.
- Copyright date:
- 2017
- Notes:
-
This is the accepted manuscript version of the article. The final version is available online from the Royal Society of Chemistry at: https://doi.org/10.1039/c7cc04188h
Journal article
Cationic silyldiazenido complexes of the Fe(diphosphine)2(N2) platform: structural and electronic models for an elusive first intermediate in N2 fixation
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