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Cu(HCO2)2(pym) (pym = pyrimidine): low-dimensional magnetic behavior and long-range ordering in a quantum-spin lattice.

Abstract:

We synthesized and structurally and magnetically characterized the novel 3D coordination polymer Cu(HCO2)2(pym) (pym = pyrimidine). The compound crystallizes in the monoclinic space group C2/c with a = 14.4639(8) A, b = 7.7209(4) A, c = 8.5172(5) A, beta = 126.076(2) degrees, and V= 768.76(7) A3. In the structure buckled layers of Cu(HCO2)2 are interconnected by pym ligands to afford 1D Cu-pym-Cu chains. Bulk magnetic susceptibility measurements show a broad maximum at 25 K that is indicative...

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Publication status:
Published

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Publisher copy:
10.1021/ic048723x

Authors


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Institution:
University of Oxford
Department:
Oxford, MPLS, Physics, Condensed Matter Physics, REF-Physics
Role:
Author
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Institution:
University of Oxford
Department:
Oxford, MPLS, Physics, Condensed Matter Physics
Role:
Author
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Journal:
Inorganic chemistry
Volume:
44
Issue:
4
Pages:
989-995
Publication date:
2005-02-05
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
URN:
uuid:285693c7-7e56-46c2-869c-f6058fb2d679
Source identifiers:
17050
Local pid:
pubs:17050
Language:
English

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