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Chemical reactivity on gas-phase metal clusters driven by blackbody infrared radiation.

Abstract:

We report the observation of chemical reactions in gas-phase Rh(n)(N2O)m(+) complexes driven by absorption of blackbody radiation. The experiments are performed under collision-free conditions in a Fourier transform ion cyclotron resonance mass spectrometer. Mid-infrared absorption by the molecularly adsorbed N2O moieties promotes a small fraction of the cluster distribution sufficiently to drive the N2O decomposition reaction, leading to the production of cluster oxides and the release of mo...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted Manuscript

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Publisher copy:
10.1002/anie.201409483

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Balaj, O. P. More by this author
Beyer, M. K. More by this author
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Engineering and Physical Sciences Research Council More from this funder
Royal Society More from this funder
Publisher:
Wiley Publisher's website
Journal:
Angewandte Chemie (International ed. in English) Journal website
Volume:
54
Issue:
4
Pages:
1357-1360
Publication date:
2015-01-16
Acceptance date:
2014-11-05
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
URN:
uuid:278e04e9-96e9-4d21-890e-959acd2df27d
Source identifiers:
499664
Local pid:
pubs:499664

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