Journal article icon

Journal article

SYNTHESIS AND COORDINATION CHEMISTRY OF A NOVEL BIS(BENZO CROWN-ETHER) SUBSTITUTED CALIX[4]ARENE THAT CAN SIMULTANEOUSLY COMPLEX CATIONS AND ANIONS

Abstract:

New Calix[4]arene compounds substituted at the lower rim by four (L3) or two (L6) benzo-15-crown-5 (2,3,5,6,8,9,11,12-octahydro-1,4,7,10,13-benzopentaoxacyclopentadecine) groups respectively have been prepared. Proton NMR co-ordination studies with sodium and potassium cations in deuteriated acetonitrile revealed that L3 forms L3·5M+ (M+ = Na+ or K+) solution stoichiometric complexes consisting of an alkali-metal cation bound in each of the four crown ether moieties and one occupying the tetr...

Expand abstract
Publication status:
Published

Actions


Access Document


Publisher copy:
10.1039/dt9950003117

Authors


Journal:
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
Issue:
19
Pages:
3117-3123
Publication date:
1995-10-07
DOI:
EISSN:
1364-5447
ISSN:
0300-9246
URN:
uuid:27578a52-d913-409b-81d4-0ff84068f516
Source identifiers:
44925
Local pid:
pubs:44925
Language:
English

Terms of use


Metrics


Views and Downloads






If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP