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The copper(II) complexes di-mu-bromo-bis{[2,6-bis(pyrazol-1-yl)pyridine]perchloratocopper(II)} and [2,6-bis(pyrazol-1-yl)pyridine]dibromocopper(II).

Abstract:

The two title compounds, di-mu-bromo-bis{[2,6-bis(pyrazol-1-yl-kappaN(2))pyridine-kappaN](perchlorato-kappaO)copper(II)}, [Cu(2)Br(2)(ClO(4))(2)(C(11)H(9)N(5))(2)], (I), and [2,6-bis(pyrazol-1-yl)pyridine]dibromocopper(II), [CuBr(2)(C(11)H(9)N(5))], (II), were synthesized by only slight modifications of the same reaction; compound (II) was formed by adding one molar equivalent of pyrazole (C(3)N(2)H(4)) to the reaction mixture of (I). Compound (I) is a bromo-bridged dinuclear copper(II) compo...

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Publication status:
Published

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Publisher copy:
10.1107/s0108270104026459

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
Acta crystallographica. Section C, Crystal structure communications More from this journal
Volume:
60
Issue:
Pt 12
Pages:
m628-m630
Publication date:
2004-12-01
DOI:
EISSN:
1600-5759
ISSN:
0108-2701
Language:
English
Pubs id:
pubs:117212
UUID:
uuid:270402ef-4009-4452-bd84-4b3d292da778
Local pid:
pubs:117212
Source identifiers:
117212
Deposit date:
2012-12-19

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