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Structural diversity in organically templated uranium sulfates

Abstract:

The potential of organic amine templates to direct the synthesis of metal sulfate frameworks has been investigated. Eight novel uranyl sulfates have been prepared using a templated uranyl sulfate precursor under hydrothermal conditions. The topologis of the isolated phases vary from the molecular (0-D), to chains (1-D) to layered (2-D) frameworks. [N4C6H 22]2[(UO2)2(SO4) 6] (USO-10) is molecular or zero-dimensional. Two different types of onedimensional uranyl-containing chains have been obse...

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Publication status:
Published

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Publisher copy:
10.1039/b209208e

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Journal:
DALTON TRANSACTIONS
Issue:
6
Pages:
1168-1175
Publication date:
2003-01-01
DOI:
ISSN:
1477-9226
URN:
uuid:2700a86b-a1b9-4c8d-a348-ac2b02173cc1
Source identifiers:
51210
Local pid:
pubs:51210
Language:
English

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