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Ferrocene aryl derivatives for the redox tagging of graphene nanoplatelets

Abstract:

Aryl derivatives of ferrocene are used for the modification of graphitic surfaces. Stronger adsorption is utilized as a route to enable the electrochemically tagging of new carbon materials. Model experiments are reported on an EPPG electrode where the adsorption of 1-(biphen-4-yl)ferrocene is found to be a factor of ca. 5 times more thermodynamically favorable than the underivatised form. Two further derivatives were also studied and the voltammetric responses of this class of ferrocenes are...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted manuscript

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Publisher copy:
10.1002/elan.201500590

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Moreira Goncalves, L More by this author
Lima, CFRAC More by this author
Vyskocil, V More by this author
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Publisher:
Wiley Online Library Publisher's website
Journal:
Electroanalysis Journal website
Volume:
28
Issue:
1
Pages:
197-202
Publication date:
2016-01-13
Acceptance date:
2015-09-10
DOI:
EISSN:
1521-4109
ISSN:
1040-0397
URN:
uuid:2676ff8b-cd44-4a6b-913e-7e0c6dbb3ecd
Source identifiers:
581537
Local pid:
pubs:581537

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