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Synthesis and reactivity of N@C60O.

Abstract:

The endohedral fullerene epoxide N@C60O was synthesised, isolated by High Performance Liquid Chromatography (HPLC), and characterised by Electron Spin Resonance (ESR). This nitrogen radical displays predominantly axial symmetry characteristics as expected for a monoadduct, evidenced by a zero-field splitting D parameter of 6.6 MHz and an E parameter of 0.5 MHz in powder at 77 K. Photo- and thermally-activated silencing of the nitrogen radical were observed, the latter showing the evolution of...

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Publication status:
Published

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Publisher copy:
10.1039/b601171c

Authors


Morton, JJ More by this author
Khlobystov, AN More by this author
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Institution:
University of Oxford
Department:
Oxford, MPLS, Materials
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Journal:
Physical chemistry chemical physics : PCCP
Volume:
8
Issue:
17
Pages:
2083-2088
Publication date:
2006-05-05
DOI:
EISSN:
1463-9084
ISSN:
1463-9076
URN:
uuid:257e8b92-e564-42bf-80ba-384ade8d4d4e
Source identifiers:
14690
Local pid:
pubs:14690
Language:
English

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