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Tin and tin-titanium as catalyst components for reversible hydrogen storage of sodium aluminium hydride

Abstract:

This paper is concerned with the effects of adding tin and/or titanium dopant to sodium aluminium hydride for both dehydrogenation and re-hydrogenation reactions during their reversible storage of molecular hydrogen. Temperature programmed decomposition (TPD) measurements show that the dehydrogenation kinetics of NaAlH4 are significantly enhanced upon doping the material with 2 mol% of tributyltin hydride, Sn(Bu)3H but the tin catalyst dopant is shown to be inferior than titanium. On the othe...

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Publisher copy:
10.1016/j.fuel.2006.03.017

Authors


Journal:
Fuel
Volume:
85
Issue:
14-15
Pages:
2141-2147
Publication date:
2006-10-05
DOI:
ISSN:
0016-2361
URN:
uuid:254ea304-6ff1-4589-b95e-27ad8aabb5e6
Source identifiers:
180205
Local pid:
pubs:180205
Language:
English
Keywords:

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