Journal article icon

Journal article

Selective radical trifluoromethylation of native residues in proteins

Abstract:

The incorporation of fluorine can not only significantly facilitate the study of proteins but also potentially modulate their function. Though some biosynthetic methods allow global residue-replacement, post-translational fluorine incorporation would constitute a fast and efficient alternative. Here, we reveal a mild method for direct protein radical trifluoromethylation at native residues as a strategy for symmetric-multifluorine incorporation on mg scales with high recoveries. High selectiv...

Expand abstract
Publication status:
Published
Peer review status:
Peer reviewed

Actions


Access Document


Files:
Publisher copy:
10.1021/jacs.7b10230

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Organic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Physical & Theoretical Chem
Role:
Author
More by this author
Role:
Author
ORCID:
0000-0003-2892-6318
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Organic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Oxford college:
Merton College
Role:
Author
ORCID:
0000-0001-8638-5308
More from this funder
Grant:
Horizon 2020 programme, Marie Skłodowska-Curie grant agreement No. 675071
Croucher Foundation More from this funder
Publisher:
American Chemical Society Publisher's website
Journal:
Journal of the American Chemical Society Journal website
Volume:
140
Issue:
5
Pages:
1568–1571
Publication date:
2018-01-05
DOI:
EISSN:
1520-5126
ISSN:
0002-7863
Pmid:
29301396
Language:
English
Pubs id:
pubs:820229
UUID:
uuid:24dd08ac-aa49-41d4-aa18-c85a291ff394
Local pid:
pubs:820229
Source identifiers:
820229
Deposit date:
2018-01-31

Terms of use


Views and Downloads






If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP