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Stereoselective conjugate addition reactions of lithium amides to alpha,beta-unsaturated chiral iron acyl complexes [(eta(5)-C5H5)Fe(CO)(PPh3)(COCH=CHR)]

Abstract:

The conjugate additions of a range of achiral and homochiral lithium amides derived from primary and secondary amines to α,β-unsaturated chiral iron acyl complexes [(η 5-C 5H 5)Fe(CO) (PPh 3)(COCHCHR)] have been studied to determine the extent of enantiorecognition in these reactions, and for the asymmetric synthesis of β-amino acids and β-lactams. Conjugate addition of achiral lithium dimethylamide to the chiral iron cinnamoyl complexes (S,E)- and (S,Z)-[(η 5-C 5H 5)Fe(CO)(PPh 3)(COCHCHPh)] ...

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
Journal:
JOURNAL OF ORGANOMETALLIC CHEMISTRY More from this journal
Volume:
689
Issue:
24
Pages:
4184-4209
Publication date:
2004-11-29
DOI:
ISSN:
0022-328X
Language:
English
Keywords:
Pubs id:
pubs:110575
UUID:
uuid:24dadef6-0535-4abf-8390-97b548120c0c
Local pid:
pubs:110575
Source identifiers:
110575
Deposit date:
2012-12-19

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