Journal article
Detailed mechanistic studies on palladium catalyzed selective C-H olefination with aliphatic alkenes: a significant influence of proton shuttling
- Abstract:
-
Directing group assisted regioselective C-H olefination with electronically biased olefins are well studied. However, the incorporation of unactivated olefins has remained largely unsuccessful. A proper mechanistic understanding of olefination involving unactivated alkenes is therefore essential for enhancing their usage in future. In this article, detailed experimental and computational mechanistic studies on palladium catalyzed C-H olefination with unactivated, aliphatic alkenes are describ...
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- Publication status:
- Published
- Peer review status:
- Peer reviewed
- Version:
- Accepted Manuscript
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(pdf, 998.0KB)
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- Publisher copy:
- 10.1021/jacs.6b10309
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Authors
Funding
Bibliographic Details
- Publisher:
- ACS Publications Publisher's website
- Journal:
- Journal of the American Chemical Society Journal website
- Volume:
- 139
- Issue:
- 2
- Pages:
- 763–775
- Publication date:
- 2016-12-20
- DOI:
- ISSN:
-
1520-5126
- Pubs id:
-
pubs:667561
- URN:
-
uri:24c6c573-6b8d-448a-8847-bf1eafb2411c
- UUID:
-
uuid:24c6c573-6b8d-448a-8847-bf1eafb2411c
- Local pid:
- pubs:667561
- Paper number:
- 2
Item Description
- Language:
- English
Terms of use
- Copyright holder:
- American Chemical Society
- Copyright date:
- 2016
- Notes:
- Copyright © American Chemical Society. This is the author accepted manuscript following peer review version of the article. The final version is available online from ACS Publications at: https://doi.org/10.1021/jacs.6b10309
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