Journal article
Detailed mechanistic studies on palladium catalyzed selective C-H olefination with aliphatic alkenes: a significant influence of proton shuttling
- Abstract:
-
Directing group assisted regioselective C-H olefination with electronically biased olefins are well studied. However, the incorporation of unactivated olefins has remained largely unsuccessful. A proper mechanistic understanding of olefination involving unactivated alkenes is therefore essential for enhancing their usage in future. In this article, detailed experimental and computational mechanistic studies on palladium catalyzed C-H olefination with unactivated, aliphatic alkenes are describ...
Expand abstract
- Publication status:
- Published
- Peer review status:
- Peer reviewed
Actions
Access Document
- Files:
-
-
(Accepted manuscript, pdf, 998.0KB)
-
- Publisher copy:
- 10.1021/jacs.6b10309
Why is the content I wish to access not available via ORA?
Bibliographic data (the information relating to research outputs) and full-text items (e.g. articles, theses, reports, etc.) arrive in ORA from several different sources. Unfortunately we are not able to make available the full-text for every research output.
Please contact the ORA team (
) if you have queries regarding unavailable content OR if you are aware of a full-text copy we can make available.
) if you have queries regarding unavailable content OR if you are aware of a full-text copy we can make available.
Content may be unavailable for the following four reasons
-
Version unsuitable
-
We have not obtained a suitable full-text for a given research output. See this page for more information.
-
Recently completed
-
Sometimes content is held in ORA but is unavailable for a fixed period of time to comply with the policies and wishes of rights holders.
-
Permissions
-
All content made available in ORA should comply with relevant rights, such as copyright. See this page for more information.
-
Clearance
-
Some thesis volumes scanned as part of the digitisation scheme funded by Dr Leonard Polonsky are currently unavailable due to sensitive material or uncleared third-party copyright content. We are attempting to contact authors whose theses are affected.
Alternative access to the full-text
You may be able to access the full-text directly from the publisher's website using the 'Publisher Copy' link in the 'Links & Downloads' box from a research output's ORA record page. This method may require an institutional or individual subscription to the journal/resource.
Authors
Funding
Bibliographic Details
- Publisher:
- ACS Publications Publisher's website
- Journal:
- Journal of the American Chemical Society Journal website
- Volume:
- 139
- Issue:
- 2
- Pages:
- 763–775
- Publication date:
- 2016-12-20
- Acceptance date:
- 2016-12-20
- DOI:
- ISSN:
-
1520-5126
Item Description
- Language:
- English
- Pubs id:
-
pubs:667561
- UUID:
-
uuid:24c6c573-6b8d-448a-8847-bf1eafb2411c
- Local pid:
- pubs:667561
- Deposit date:
- 2017-01-06
Terms of use
- Copyright holder:
- American Chemical Society
- Copyright date:
- 2016
- Notes:
- Copyright © American Chemical Society. This is the author accepted manuscript following peer review version of the article. The final version is available online from ACS Publications at: https://doi.org/10.1021/jacs.6b10309
If you are the owner of this record, you can report an update to it here: Report update to this record