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Detailed mechanistic studies on palladium catalyzed selective C-H olefination with aliphatic alkenes: a significant influence of proton shuttling

Abstract:

Directing group assisted regioselective C-H olefination with electronically biased olefins are well studied. However, the incorporation of unactivated olefins has remained largely unsuccessful. A proper mechanistic understanding of olefination involving unactivated alkenes is therefore essential for enhancing their usage in future. In this article, detailed experimental and computational mechanistic studies on palladium catalyzed C-H olefination with unactivated, aliphatic alkenes are describ...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted Manuscript

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Publisher copy:
10.1021/jacs.6b10309

Authors


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Department:
Oxford, MPLS, Chemistry, Organic Chemistry
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Department:
St Hildas College
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Funding agency for:
Peng, Q
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Funding agency for:
Peng, Q
Publisher:
ACS Publications Publisher's website
Journal:
Journal of the American Chemical Society Journal website
Volume:
139
Issue:
2
Pages:
763–775
Publication date:
2016-12-20
DOI:
ISSN:
1520-5126
Pubs id:
pubs:667561
URN:
uri:24c6c573-6b8d-448a-8847-bf1eafb2411c
UUID:
uuid:24c6c573-6b8d-448a-8847-bf1eafb2411c
Local pid:
pubs:667561
Language:
English

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