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High resolution spectroscopy of Ar-CH4 and Kr-CH4 in the 7 mu region (j=1 <- 0 transition)

Abstract:

Diode laser spectra of the rare gas - spherical top van der Waals complexes Ar-CH4 and Kr-CH4 were measured in the wavelength region near 1310 cm-1 and assigned. The most prominent lines of both complexes exhibit three dense but well resolved RP0, QR0, and RQ0 branches, correlated to the R(0) transition of the triply degenerate bending vibration v4 of methane, CH4. A model Hamiltonian based on Coriolis coupled states was applied for the assignment, analysis and fitting of the spectra to withi...

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Publication status:
Published

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Journal:
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES
Volume:
53
Issue:
8
Pages:
725-732
Publication date:
1998-08-05
ISSN:
0932-0784
URN:
uuid:24abb260-bcdf-4f4a-a0d6-cb4a064b57e4
Source identifiers:
36636
Local pid:
pubs:36636
Language:
English

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