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B-C activation in highly alkylated carborane monoanions partnered with cationic transition metal fragments: observations and comments

Abstract:
Cage decomposition products of the highly methylated, weakly coordinating, carborane anion [1-H-closo-CB11Me11]- are described. These arise both from well-defined metal complexes of [1-H-closo-CB11Me11]- that already have BCH3⋯[M] interactions and from attempts to partner this anion with other metal centres. In all cases the decomposition results in B-CH 3 bond cleavage and solvent activation to form products with B-aryl or B-Cl vertices. © 2004 Published by Elsevier B.V.
Publication status:
Published

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Publisher copy:
10.1016/j.ica.2004.09.048

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
INORGANICA CHIMICA ACTA More from this journal
Volume:
358
Issue:
5
Pages:
1571-1580
Publication date:
2005-03-15
DOI:
ISSN:
0020-1693
Language:
English
Keywords:
Pubs id:
pubs:51705
UUID:
uuid:2480e6e0-7d35-4d1a-aef4-e5b59fe32114
Local pid:
pubs:51705
Source identifiers:
51705
Deposit date:
2012-12-19

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