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Fast, long-range electron-transfer reactions of a "blue" copper protein coupled non-covalently to an electrode through a stilbenyl thiolate monolayer.

Abstract:
A self-assembled monolayer (SAM), formed by the insitu saponification of a stilbenyl thioacetate on a gold electrode, yields fast electron transfer (ET)(the exchange rate at zero driving force exceeds 1600 s-1) with adsorbed molecules of the blue copper protein, azurin, over a distance exceeding 15 angstroms .
Publication status:
Published

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Publisher copy:
10.1039/b312936e

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
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Journal:
Chemical communications (Cambridge, England)
Volume:
10
Issue:
3
Pages:
316-317
Publication date:
2004-02-05
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
URN:
uuid:246af805-dea1-49a2-a53a-9942689371be
Source identifiers:
32606
Local pid:
pubs:32606

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