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FDIONIC18 atomic charges of sulfur in ionic liquids: experiments and calculations

Abstract:

Experimental near edge X-ray absorption fine structure (NEXAFS) spectra, X-ray photoelectron (XP) spectra and Auger electron spectra are reported for sulfur in ionic liquids (ILs) with a range of chemical structures. These values provide experimental measures of the atomic charge in each IL and enable evaluation of the suitability of NEXAFS spectroscopy and XPS for probing relative atomic charge of sulfur. In addition, we use Auger electron spectroscopy to show that when XPS binding energies ...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1039/C7FD00155J

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Funding agency for:
Lovelock, K
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Funding agency for:
Lovelock, K
Publisher:
Royal Society of Chemistry Publisher's website
Journal:
Faraday Discussions Journal website
Volume:
206
Pages:
183-201
Publication date:
2017-06-08
Acceptance date:
2017-06-08
DOI:
EISSN:
1364-5498
ISSN:
1359-6640
Source identifiers:
709996
Pubs id:
pubs:709996
UUID:
uuid:245dd00f-8589-45c1-ae5d-d4592d9de314
Local pid:
pubs:709996
Deposit date:
2017-07-31

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