Journal article
Ag-catalyzed stereoselective aminosulfonylation of alkynes
- Abstract:
- A silver-catalyzed intermolecular aminosulfonylation of terminal alkynes with sodium sulfinates and TMSN3 is reported. This three component reaction proceeds through sequential hydroazidation of the terminal alkyne, and addition of a sulfonyl radical to the resultant vinyl azide. The method enables the stereoselective synthesis of a wide range of β-sulfonyl enamines without electron-withdrawing groups on the nitrogen atom, which are found to be suitable for a variety of further transformations.
- Publication status:
- Published
- Peer review status:
- Peer reviewed
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(Version of record, pdf, 1.1MB)
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- Publisher copy:
- 10.1002/anie.201705122
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Authors
Funding
+ Engineering and Physical Sciences Research Council
More from this funder
Funding agency for:
Anderson, E
Grant:
EP/M019195/1
+ National Natural Science Foundation of China
More from this funder
Funding agency for:
Bi, X
Grant:
21502017
Bibliographic Details
- Publisher:
- Wiley Publisher's website
- Journal:
- Angewandte Chemie International Edition Journal website
- Volume:
- 56
- Issue:
- 44
- Pages:
- 13805-13808
- Publication date:
- 2017-06-19
- Acceptance date:
- 2017-06-17
- DOI:
- EISSN:
-
1521-3757
- ISSN:
-
1433-7851
- Source identifiers:
-
702100
Item Description
- Keywords:
- Pubs id:
-
pubs:702100
- UUID:
-
uuid:2419002c-8873-470f-b457-dae31e4f8408
- Local pid:
- pubs:702100
- Deposit date:
- 2017-06-28
Terms of use
- Copyright holder:
- © 2017 Ning, et al
- Copyright date:
- 2017
- Notes:
- ©The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
- Licence:
- CC Attribution (CC BY)
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