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Journal article

Synthesis of propargylic fluorides from allenylsilanes.

Abstract:
Allenylsilanes reacted at room temperature in acetonitrile with Selectfluor, an electrophilic fluorinating reagent, to give secondary propargylic fluorides in moderate to good yields; mechanistically, a side-product resulting from a 1,2-silyl shift testifies to the presence of a cationic intermediate.
Publication status:
Published

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Publisher copy:
10.1039/b610013a

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
Journal:
Chemical Communications More from this journal
Issue:
39
Pages:
4113-4115
Publication date:
2006-10-01
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
Language:
English
Pubs id:
pubs:33624
UUID:
uuid:23b4d698-23b1-42ee-b13d-cba478587631
Local pid:
pubs:33624
Source identifiers:
33624
Deposit date:
2012-12-19

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